EMMD - Electrochemistry, Molecular Materials and Devices

EMMD (Electrochemistry, Molecular Materials and Devices) research activities are devoted to molecular materials, from molecules to materials and from materials to devices. Electrochemical techniques are used to synthesize, to immobilize and to detect chemical or biological species. The synthetic aspect relates to the synthesis and functionalization of macrocycles (porphyrins, phthalocyanines…) and polymers. The analytical aspect 1) exploits the redox properties of compounds or sensitive layers (biomaterials, conducting polymers, charge-transfer complexes, …) for the characterization and the detection of biomolecules or chemical pollutants in sensor devices; 2) to apprehend reaction mechanism of molecular processes. Our projects are focused on applications in the fields of environment, health and food industry.

VOROTYNTSEV Mikhail Voir la fiche profil en français Français (FR)

image-profil
  • Address :

    ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
    Bât. MIRANDE - Aile B - Bureau B413
    9 Avenue Alain Savary
    21000 Dijon – France

  • Tél : (+33) 380 396 104
  • mv@u-bourgogne.fr
  • Lomonosov Moscow State University, Assist. Professor (1970-78)
  • Theoretical Department, Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR
    Senior/Leading/Principal Researcher (1979-98)
  • LSEO/ICMUB-UMR 5260/6302 CNRS, Université de Bourgogne, Dijon, Professeur Associé (1997-98),
    Directeur de Recherche 2 au CNRS (1998-2011), Directeur de Recherche Emerite (2011-)

1. Synthesis and characterization of novel polymeric materials on the basis of porphine macrocycle
2. Fundamental principles of functioning of bromate-based flow batteries

Publications during the last 5 years (2015-2019):

  1. Theoretical Analysis of Changes in the Solution Composition during Anodic Electrolysis of Bromide
    M. A. Vorotyntsev, A. E. Antipov
    Electrochim. Acta, 2019, vol. 323, 134799 (November issue)   DOI: 10.1016/j.electacta.2019.134799
  2. Hydrogen-bromate flow battery: can one reach both high bromate utilization and specific power?
    A. D. Modestov., D. V. Konev, A. E. Antipov, M. A. Vorotyntsev
    J. Solid State Electrochem., 2019, vol. 23, 3075-3088   DOI: 10.1007/s10008-019-04371-w
  3. Theoretical Analysis of Changes in the Solution Composition during Anodic Electrolysis of Bromide
    M. M. Petrov, D. V. Konev, A. E. Antipov, N. V. Kartashova, V. V. Kuznetsov, M. A. Vorotyntsev
    Russ. J. Electrochem., 2019, vol. 55, n.11, 1058-1067   DOI: 10.1134/S1023193519110120
  4. Uniformity ansatz for inverse dielectric function of spatially restricted nonlocal polar medium as a novel approach for calculation of electric characteristics of ion-solvent system
    M. A. Vorotyntsev, A. A. Rubashkin
    Chem. Phys., 2019, vol. 521, 14-24     DOI: 10.1016/j.chemphys.2019.01.003
  5. Electrochemical synthesis of polypyrrole in powder form
    O. I. Istakova, D. V. Konev, A. T. Glazkov, T. O. Medvedevа, E. V. Zolotukhina, M. A. Vorotyntsev
    J. Solid State Electrochem., 2019, vol. 23, 251–258     DOI: 10.1007/s10008-018-4129-2
  6. Electrochemically driven evolution of Br-containing aqueous solution composition
    M. M. Petrov, D. V. Konev, V. V. Kuznetsov, A. E. Antipov, A. T. Glazkov, M. A. Vorotyntsev
    J. Electroanal. Chem.. 2019, vol. 836, 125-133   DOI: 10.1016/j.jelechem.2019.01.070
  7. Bromate-Anion Electroreduction at Rotating Disc Electrode under Steady-State Conditions: Comparison of Numerical and Analytical Solutions for Convective Diffusion Equations in Excess of Protons
    A. E. Antipov, M. A. Vorotyntsev, D. V. Konev, E. M. Antipov
    Russ. J. Electrochem., 2019, vol. 55, 458-466   DOI: 10.1134/S1023193519050033
  8. Electroreduction of the Bromate Anion on a Microlectrode in Excess Acid: Solution of the Inverse Kinetic Problem
    O. A. Goncharova, A. T. Glazkov, K. V. Lizgina, A. A. Piryazev, S. L. Koryakin, D. V. Konev, M. A. Vorotyntsev, V. B. Mintsev
    Doklady Chemistry, 2019, vol. 484, Part 1, 12–15   DOI: 10.1134/S0012500819010063
  9. Novel procedure towards approximate analytical description of bromate-anion reduction at rotating disk electrode under steady-state transport conditions
    M. A. Vorotyntsev, A. E. Аntipov
    Electrochim. Acta, 2018, vol. 289, 272-282
  10. Evolution of Anolyte Composition in the Oxidative Electrolysis of Sodium Bromide in a Sulfuric Acid Medium
    M. M. Petrov, P. A. Loktionov, D. V. Konev, A. E. Antipov, E. A. Astafiev, M. A. Vorotyntsev
    Russ. J. Electrochem., 2018, vol. 54, 1233-1242
  11. Efficiency of Pyrrole Electropolymerization under Various Conditions
    O. I. Istakova, D. V. Konev, T. O. Medvedeva, E. V. Zolotukhina, M. A. Vorotyntsev
    Russ. J. Electrochem., 2018, vol. 54, 1243-1251
  12. A New Approach in the Theory of Space-Confined Nonlocal Dielectric Media
    M. A. Vorotyntsev, A. A. Rubashkin, A. E. Antipov
    Russ. J. Electrochem., 2018, vol. 54, 879-885
  13. Palladium Nanoparticles–Polypyrrole Composite as Effective Catalyst for Fluoroalkylation of Alkenes
    T. V. Gryaznova, M. N. Khrizanforov, K. V. Kholin, M. A. Vorotyntsev, K. V. Gor’kov, N. V. Talagaeva, M. V. Dmitrieva, E. V. Zolotukhina, Y. H. Budnikova
    CatalysisLetters, 2018, vol. 148, 3119–3125
  14. Bromate Reaction on a Rotating Disc Electrode: A New Method of Obtaining Approximate Analytical Solutions for Stationary Regime
    M. A. Vorotyntsev, A. E. Antipov, M. M. Petrov, R. D. Pichugov, E. I. Borisevich, E. M. Antipov, S. M. Aldoshin
    Doklady Chemistry, 2018, vol. 483, Part 1, 256–260
  15. Pd-Polypyrrole Nanocomposite in Environmentally Friendly Synthesis of Vinylnitriles Using K4 Fe(CN)6
    T. V. Magdesieva, O. M. Nikitin, O. V. Polyakova, P. K. Sazonov, E. V. Zolotukhina, K. V. Gor'kov, A. V. Samarov, M. A. Vorotyntsev
    Chem. Select, 2018, vol. 3 (16), 4237-4243
  16. Electroactive Component of Pd-Polypyrrole Composite and its Catalytic Properties in Cyanation Reaction of Styryl Bromates
    O. M. Nikitin, T. V. Magdesieva, O. V. Polyakova, P. K. Sazonov, K.V. Gor'kov, E. V. Zolotukhina, M.A. Vorotyntsev
    Russ. J. Electrochem., 2018, vol. 54, 608-611
  17. Electrocatalytic properties of manganese and cobalt polyporphine films toward oxygen reduction reaction
    D. V. Konev, O. I. Istakova, B. Dembinska, M. Skunik-Nuckowska, C. H. Devillers, O. Heintz, P. J. Kulesza, M. A. Vorotyntsev
    J. Electroanal. Chem., 2018, vol. 816, 83-91
  18. A novel hydrogen-bromate flow battery for air deficient environment: proof-of-concept study
    A. D. Modestov, D. V. Konev, O. V. Tripachev, A. E. Antipov, Y. V. Tolmachev, M. A. Vorotyntsev
    Energy Technology, 2018, vol. 6, 242-245
  19. Bromate electroreduction from acidic solution at rotating disc electrode. Theoretical study of the steady-state convective-diffusion transport for excess of bromate ions compared to protons
    M. A. Vorotyntsev, A. E. Antipov
    ElectrochimicaActa, 2018, vol. 261, 113-126
  20. Maximum Current Density in the Reduction of the Bromate Anion on a Rotating Disk Electrode: Asymptotic Behavior at Large Thicknesses of the Diffusion Layer
    A. E. Antipov, M. A. Vorotyntsev
    Russ. J. Electrochem., 2018, vol. 54, № 2, 186-194
  21. Surprising dependence of the current density of bromate electroreduction on the microelectrode radius as manifestation of the autocatalytic redox-cycle (EC″) reaction mechanism
    D. V. Konev, A. E. Antipov, M. M. Petrov, M. A. Shamraeva, M. A. Vorotyntsev
    Electrochem. Comm., 2018, vol. 86, 76-79
  22. Bromate Anion Reduction at Rotating Disk Electrode in Steady State under Excess of Protons: Numerical Solution of the Convective Diffusion Equations at Equal Diffusion Coefficients of Components
    A. E. Antipov, M. A. Vorotyntsev
    Russ. J. Electrochem., 2018, vol. 54, № 1, 62-69
  23. Bromate electroreduction from sulfuric acid solution at rotating disk electrode: experimental study
    A. D. Modestov, D. V. Konev, A. E. Antipov, M. M. Petrov, R. D, Pichugov, M. A. Vorotyntsev
    Electrochim. Acta, 2018, vol. 259, 655-663
  24. Bromate electroreduction from acidic solution at spherical microelectrode under steady-state conditions: theory for the redox-mediator autocatalytic (EC") mechanism
    M. A. Vorotyntsev, A. E. Antipov
    Electrochim. Acta, 2017, vol. 258, 544-553
  25. Bromate anion reduction: novel autocatalytic (EC") mechanism of electrochemical processes. Its implication for redox flow batteries of high energy and power densities
    M. A. Vorotyntsev, А. Е. Antipov, D. V. Konev
    Pure Applied Chemistry, 2017, vol. 89, № 10, 1429–1448
  26. Pd–PPy nanocomposite on the surface of carbon nanotubes: synthesis and catalytic activity
    K. V. Gor'kov, N. V. Talagaeva, J.-C. Hierso, I. S. Bezverkhyy, P. A. Pisareva, M. A. Vorotyntsev, E.. Zolotukhina
    Surface Innov., 2017, vol. 5, 121-129 
  27. Generalized Nernst Layer Model for Convective-Diffusion Transport. Numerical Solution for Bromide Ion Electroreduction on Inactive Rotating Disk Electrode under Steady State Conditions
    А. Е. Antipov, M. A. Vorotyntsev
    Russ. J. Electrochem., 2017, vol. 53, № 10, 1100-1108
  28. The Importance of V. G. Levich’s Research in the Development of Modern Electrochemistry
    J. Ulstrup, M. A. Vorotyntsev, A. D. Davydov, B. M. Grafov
    Russ. J. Electrochem., 2017, vol. 53, № 9, 893-896 
  29. Mediator Reduction of Bromate Anion at Rotating Disk Electrode under Steady-state Conditions for High Current Densities
    M. A. Vorotyntsev, А. Е. Antipov
    Russ. J. Electrochem., 2017, vol. 53, № 9, 919–931
  30. Electrochemistry of electroactive materials: WEEM-2015 and EEM-2016
    M. A. Vorotyntsev
    Electrochim. Acta, 2017, vol. 246, 1259-1260
  31. Bromate electroreduction from acidic solution at rotating disk electrode. Theory of steady-state convective-diffusion transport
    M. A. Vorotyntsev, А. Е. Antipov
    Electrochim. Acta, 2017, vol. 246, 1217-1229
  32. Electrostatic contribution to the ion solvation energy: cavity effects
    M. A. Vorotyntsev, A. A. Rubashkin
    Phys. Chem. Liquids, 2017, vol. 55, Issue 2, 141-152
  33. Synthesis and electrocatalytic properties of palladium-polypyrrole nanocomposite in formaldehyde oxidation reaction
    V. K. Gor'kov, E. V. Zolotukhina, E. R. Mustafina, M. A. Vorotyntsev
    Russ. J. Electrochem., 2017, vol. 53, № 1, 49-57 
  34. 1D model of steady-state discharge process in hydrogen-bromate flow battery
    M. A. Vorotyntsev, А. Е. Antipov, Yu. V. Tolmachev
    Electrochim. Acta, 2016, vol. 222C, 1555-1561   
  35. Electrochemical Synthesis of Cobalt Polyporphine Films
    O. I. Istakova, D. V. Konev, C. H. Devillers, M. A. Vorotyntsev, A. S. Zyubin, E. M. Antipov, S. M. Aldoshin, 
    Doklady Physical Chemistry, 2016, vol. 471, Part 1, 181–184
  36. Generalization of the Nernst Layer Model to Take into Account the Difference in Diffusivity between the Components of the System in Bromate Reduction in Steady-State One-Dimensional Mode: Current Limiting by Proton Transport
    А. Е. Antipov, M. A. Vorotyntsev, Yu. V. Tolmachev, E. M. Antipov, S. M. Aldoshin
    Doklady Physical Chemistry, 2016, vol. 471, 185-189 
  37. Electropolymerization of magnesium 5,15-di(n-methoxyphenyl)porphin
    D. V. Konev, K. V. Lizgina, O. I. Istakova, V. E. Baulin, I. P. Kalashnikova, C. H. Devillers, M. A. Vorotyntsev
    Russ. J. Electrochem., 2016, vol. 52, № 12, 1150-1158 
  38. Generalized Nernst Layer Model: application to bromate anion electroreduction. Theory for stationary 1D regime for proton transport limitations
    M. A. Vorotyntsev, А. Е. Antipov
    ChemElectrochem, 2016, vol. 3, Issue 12, 2227–2242
  39. Electrochemical route to Co(II) polyporphine
    O. I. Istakova, D. V. Konev, A. S. Zyubin, C. H. Devillers, M. A. Vorotyntsev
    J. Solid State Electrochem., 2016, vol. 20, 3189–3197
  40. Reduction of bromate anion via autocatalytic redox-mediation by Br2/Br- redox couple. Theory for stationary 1D regime. Effect of different Nernst layer thicknesses for reactants
    M. A. Vorotyntsev, А. Е. Antipov
    J. Electroanal. Chem., 2016, vol. 779, 146-155
  41. Efficient synthesis of a new electroactive polymer of Co(II) porphine by in-situ replacement of Mg(II) inside Mg(II) polyporphine film.
    S. D. Rolle, D. V. Konev, C. H. Devillers, K. V. Lizgina, D. Lucas, C. Stern, F. Herbst, O. Heintz, M. A. Vorotyntsev
    Electrochim. Acta, 2016, vol. 204, 276-286
  42. Electrocatalytic activity of nanostructured palladium-polypyrrole composite in formaldehyde oxidation reaction
    K. V. Gor'kov, E. V. Zolotukhina, E. R. Mustafina, M. A. Vorotyntsev, E. M. Antipov, S. M. Aldoshin
    Doklady Physical Chemistry, 2016, vol. 467, 37-40
  43. Bromate anion electroreduction on inactive RDE under steady-state conditions. Numerical study of ion transport processes and comproportionation reaction
    А. Е. Antipov, M. A. Vorotyntsev
    Russ. J. Electrochem., 2016, vol. 52, № 10, 925-932
  44. Synthesis of cobalt polyporphine films and their electrocatalytic properties in oxygen electroreduction reaction
    D. V. Konev, K. V. Lizgina, D. K. Khairullina, M. A. Shamraeva, C. H. Devillers, M. A. Vorotyntsev
    Russ. J. Electrochem., 2016, vol. 52, No. 8, 778–787
  45. Electrochromic properties of Prussian Blue-polypyrrole composite films in dependence on parameters of synthetic procedure
    N.V. Talagaeva, E.V. Zolotukhina, P. A. Pisareva, M.A. Vorotyntsev
    J. Solid State Electrochem., 2016, vol. 20, № 5, 1235-1240 
  46. Bromate anion electroreduction in acidic solutions on inactive RDE under steady-state conditions. Numerical modeling of the process under conditions of bromate-anion excess compared to protons
    M. A. Vorotyntsev, А. Е. Antipov, Yu. V. Tolmachev, E. M. Antipov, S. M. Aldoshin
    Doklady Chemistry, 2016, vol. 468, № 1, 141-147
  47. Novel electrochromic films based on Prussian Blue and polypyrrole
    N.V. Talagaeva, E.V. Zolotukhina, P.A. Pisareva, M.A. Vorotyntsev
    Mendeleev Commun., 2016, vol. 26, 119-120
  48. Electrostatic Contribution to the Ion Solvation Energy: Overscreening Effect in the Nonlocal Dielectric Response of the Polar Medium
    A. A. Rubashkin, M. A. Vorotyntsev
    CurrentPhys. Chem., 2016, vol. 6, 120-129 
  49. The method of double cathodic-anodic potential (current) pulses for synthesis of composite coatings Prussian blue–polypyrrole on optically transparent electrodes
    N.V. Talagaeva, P.A. Pisareva, A. K. Grebenko, M.A. Vorotyntsev, E.V. Zolotukhina
    Russ. J. Electrochem., 2016, vol.52, № 1, 46-52
  50. Spectroelectrochemical Determination of the Redox Equivalent of Magnesium Porphine in the Course of Its Electrooxidation
    O. I. Istakova, D. V. Konev, M. A. Vorotyntsev, E. M. Antipov, S. M. Aldoshin
    Doklady Physical Chemistry, 2016, vol. 466, part 1, 15-18 
  51. Nonlocal Electrostatic Theory of Ion Solvation: a Combination of the Overscreening Effect in the Dielectric Response of the Medium with a Smeared Ion Charge Distribution
    A. A. Rubashkin, M. A. Vorotyntsev, E. M. Antipov, S. M. Aldoshin
    Doklady Physical Chemistry, 2015, vol. 464, 198-201
  52. Stability of Prussian Blue-polypyrrole (PB/pPy) composite films synthesized via one-step redox-reaction procedure
    N. V. Talagaeva, E. V. Zolotukhina, I. Bezverkhyy, D. V. Konev, Y. Lacroute, E. Yu. Maksimova, S. L. Koryakin, M. A. VorotyntsevJ. Solid State Electrochem., 2015, vol. 19, 2701-2709
  53. In situ UV-visible spectroelectrochemistry in the course of oxidative monomer electrolysis as a tool to characterize the molecular structure of poly(Mg(II)porphine)
    D. V. Konev, O. I. Istakova, О. А. Sereda, М. А. Shamraeva, C.H. Devillers, M. A. Vorotyntsev
    Electrochim. Acta, 2015, vol. 179, 315-325         
  54. Electroreduction of halogen oxoanions via autocatalytic redox mediation by halide anions: novel EC" mechanism. Theory for stationary 1D regime
    M. A. Vorotyntsev, D. V. Konev, Y. V. Tolmachev
    Electrochim. Acta, 2015, vol. 173, 779-795   
  55. Silver/ion exchanger nanocomposites as low-temperature redox-catalysts for methanal oxidation
    E. A. Sakardina, T. A. Kravchenko, E. V. Zolotukhina, M. A. Vorotyntsev
    Electrochim. Acta, 2015, vol. 179, 364-371 
  56. Energy cycle based on a high specific energy aqueous flow battery and its potential use for fully electric vehicles and for direct solar-to-chemical energy conversion
    Y. V. Tolmachev, A. Pyatkivskiy, V. V. Ryzhov, D. V. Konev, M. A. Vorotyntsev
    J. Solid State Electrochem., 2015, vol. 19, 2711-2722 
  57. Electropolymerization of non-substituted Mg(II) porphine: Effects of proton acceptor addition
    D. V. Konev, C. H. Devillers, K. V. Lizgina, V. E. Baulin, M. A. Vorotyntsev
    J. Electroanal. Chem., 2015, vol. 737, 235-242

 

Selected recent plenary, keynote and invited lectures at conferences (2014-2019):

  • Synthesis of novel transition-metal containing representatives of the polyporphine family
    D. V. Konev, O. I. Istakova, B. Dembinska, M. Skunik-Nuckowska, C. H. Devillers, O. Heintz, P. J. Kulesza, M. A. Vorotyntsev
    International Workshop on the Electrochemistry of Electroactive Materials (WEEM-2019), 2019, Borovets, Bulgaria
  • Surprising dependence of the current density of bromate electroreduction on the microelectrode radius
    M. A. Vorotyntsev, A. E. Antipov, D. V. Konev
    International conference "ion transport in organic and inorganic membranes", 2019, Sochi, Russia
  • Electrochemical route to Co(II) and Mn(II) polyporphines and their electrocatalytic properties towards oxygen reduction reaction
    D. V. Konev, O. I. Istakova, B. Dembinska, M. Skunik-Nuckowska, C. H. Devillers, O. Heintz, P. J. Kulesza, M. A. Vorotyntsev
    5th International Symposium on Surface Imaging/Spectroscopy at the Solid/Liquid (ISSIS), 2018, Krakow, Poland
  • Paradoxical predictions of the mediator-autocatalysis theory of electrochemical processes and their experimental verification
    M. A. Vorotyntsev, A. E. Antipov, D. V. Konev, R. D. Pichugov
    International conference "ion transport in organic and inorganic membranes", 2018, Sochi, Russia
  • Bromate reduction at rotating disk electrode via autocatalytic redox-cycle mechanism: predictions vs. experimental data
    M. A. Vorotyntsev, A. E. Antipov, D. V. Konev, A. D. Modestov
    International conference "67th Annual Meeting of the International Society of Electrochemistry", 2017, Providence, USA
  • Novel autocatalytic mechanism of electrochemical processes and its implications for electrochemical energy systems
    M. A. Vorotyntsev, Yu. V. Tolmachev, A. E. Antipov
    International conference "XII ECHEMS", 2017, Milano Maritima, Italy
  • Bromate anion reduction via autocatalytic cycle and its implications for electrical energy sources
    M. A. Vorotyntsev, Yu. V. Tolmachev, D. V. Konev, A. E. Antipov
    International conference "Ion transport in organic and inorganic membranes", 2017, Sochi, Russia
  • Novel autocatalytic mechanism of electrochemical processes and its implications for energy sources
    Vorotyntsev M.A., Antipov А.Е., Konev D.V., Tolmachev Yu.V.
    XX Mendeleev Congress on Pure and Applied Chemistry, 2016, Ekaterinburg, Russia
  • Novel Autocatalytic Mechanism of Electrochemical Processes and Its Implications for Electrical Energy Sources
    M. A. Vorotyntsev, Yu. V. Tolmachev, D. V. Konev, A. E. Antipov
    International conference "Ion transport in organic and inorganic membranes", 2016, Sochi, Russia
  • Porphine-Based Electroactive Materials
    D. V. Konev, C. H. Devillers, M. A. Vorotyntsev
    French-Russian Conference on Soft-Matter Systems, 2015, Moscow, Russia
  • Spectroelectrochemistry as a tool to characterize the molecular structure of conjugated polymer films
    D. V. Konev, О. I. Istakova, O. A. Sereda, M. A. Shamraeva, C. H. Devillers, M. A. Vorotyntsev
    4th International Symposium on Surface Imaging/Spectroscopy at the Solid/Liquid Interface (ISSIS 2015), 2015, Krakow, Poland
  • Spectroelectrochemistry in the course of oxidative electrolysis as a tool to characterize the molecular structure of electroactive polymer based on Mg(II) porphine
    D. V. Konev, О. I. Istakova, O. A. Sereda, M. A. Shamraeva, C. H. Devillers, M. A. Vorotyntsev
    International Workshop on the Electrochemistry of Electroactive Materials (WEEM-2015), 2015, Bad Herrenalb, Germany
  • Novel in situ method for measurement of the dependence of the specific electroconductivity of a thin film at electrode surface on its potential
    М. А. Воротынцев, Д. В. Конев
    12th International meeting “Fundamental problems of Solid-State Ionics”, 2014, Chernogolovka, Russia
  • AFM study of conducting polymer films near electrode's edge or grown on microband electrode
    M. A. Vorotyntsev, D. V. Konev, U. Lange, Y. V. Tolmachev, M. Skompska
    International conference "Ion transport in organic and inorganic membranes", 2014, Agoi, Russia

 

Electrochemistry, Electroactive Polymers, Functional and Nanostructured Materials, Electrochemical Energetics, Mixed Conductors, Transport Phenomena, Physics of Interfaces, Chemical Kinetics, Physics of Condensed Matters, Electron Transfer, Biophysics