EMMD - Electrochemistry, Molecular Materials and Devices

EMMD (Electrochemistry, Molecular Materials and Devices) research activities are devoted to molecular materials, from molecules to materials and from materials to devices. Electrochemical techniques are used to synthesize, to immobilize and to detect chemical or biological species. The synthetic aspect relates to the synthesis and functionalization of macrocycles (porphyrins, phthalocyanines…) and polymers. The analytical aspect 1) exploits the redox properties of compounds or sensitive layers (biomaterials, conducting polymers, charge-transfer complexes, …) for the characterization and the detection of biomolecules or chemical pollutants in sensor devices; 2) to apprehend reaction mechanism of molecular processes. Our projects are focused on applications in the fields of environment, health and food industry.

ROUSSELIN Yoann Voir la fiche profil en français Français (FR)

image-profil
  • Address :

    ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
    Bât. MIRANDE - Aille B - Bureau B-105
    9 Avenue Alain Savary
    21000 Dijon – France

  • Tél : (+33) 380 393 835
  • yoann.rousselin@u-bourgogne.fr

After finishing my Ph.D. in organic chemistry, dedicated to developing new synthesis methods of polyazamacrocycles, have acquired some knowledge in spectroscopy (IR, GC-MS, NMR, Maldi-TOF, X-ray diffraction), especially in crystallography. I turned in the field of X-ray diffraction where I am now in charge of the platform of X-ray diffraction (crystal/powder structure determination, publication, powder and single crystal X-ray, system maintenance, upgrade). 

Mission:
- Provide technical support and data processing/analysis
- Procure, install, maintain and troubleshoot scientific equipment
- Plan and execute scientific experiments
- Create posters and presentations for international conferences and publish scientific results in peer-reviewed journals

Application fields:
-Single Crystal X-Ray Diffraction: study of absolute configurations of chiral compounds possessing an active ingredient (drugs), study of intermetallic distances as a function of temperature of new compounds with luminescence properties, study of the coordination mode of new medical imaging tracers...
-Powder X-Ray Diffraction: polymorphism study, quality control (alloys, drugs, polymers...), crystallinity rate (polymers, catalysts...), comparative study of samples after treatments, research of the chemical composition of an unknown product expertise, geology, civil engineering...

Equipment:
- Automatic diffractometer Bruker Nonius Kappa APEX II (CCD / sealed tube Mo) and Bruker D8 Venture Photon 100 (CMOS / sealed tube Mo with Triumph monochromator / sealed tube Cu high brilliance microfocus) for the analysis of single crystals 
- Automatic diffractometer Theta - 2 Theta Panalytical Empyrean for the analysis of powder (Cu) 

 Patent
o 2014
• Synthesis of imidazo[1,2-a]pyrazin-4-ium salts for the synthesis of 1,4,7-triazacyclononane (TACN) and N- and/or C-functionalized derivatives thereof Denat, F., Desogere, P., Bernhard, C., Rousselin, Y. & Boschetti, F. Centre National de la Recherche Scientifique, Fr.; Universite de Bourgogne . US20140142298A1. 2014.

 Publications
o 2018
• Electrochemistry of Bis(pyridine)cobalt (Nitrophenyl)corroles in Nonaqueous Media. Jiang, X., Naitana, M. L., Desbois, N., Quesneau, V., Brandes, S., Rousselin, Y., Shan, W., Osterloh, W. R., Blondeau-Patissier, V., Gros, C. P., Kadish, K. M., Inorg Chem 2018, 57, 1226-1241.
• Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ2O1,O2)stannate(IV). Sarr, B., Diop, C. A. K., Sidibé, M., Rousselin, Y., Acta Crystallographica Section E Crystallographic Communications 2018, 74, 502-504.
• Effects of preorganization in the chelation of UO22+ by hydroxamate ligands: cyclic PIPO−vs. linear NMA−. Sornosa-Ten, A., Jewula, P., Fodor, T., Brandès, S., Sladkov, V., Rousselin, Y., Stern, C., Chambron, J.-C., Meyer, M., New Journal of Chemistry 2018, 42, 7765-7779.
• A Comparative IRMPD and DFT Study of Fe(3+) and UO2(2+) Complexation with N-Methylacetohydroxamic Acid. Terencio, T., Roithova, J., Brandes, S., Rousselin, Y., Penouilh, M. J., Meyer, M., Inorg Chem 2018, 57, 1125-1135.
o 2017
• Synthesis, spectroscopic, cyclic voltammetry properties and molecular structure of the thiocyanato-N meso-tetratolylporphyrinato zinc(II) ion complex. Denden, Z., Harhouri, W., Ben Haj Hassen, L., Rousselin, Y., Saint-Aman, E., Nasri, H., Journal of Molecular Structure 2017, 1133, 472-478.
• Cadmium Metal–Organic Frameworks Based on Ditopic Triazamacrocyclic Linkers: Unusual Structural Features and Selective CO2 Capture. Feuchter, H., Ortiz, G., Rousselin, Y., Bessmertnykh-Lemeune, A., Brandès, S., Crystal Growth & Design 2017, 17, 3665-3676.
• Regioselective Synthesis of Mono- and Dispiropyrazoline Derivatives via 1,3-dipolar Cycloaddition with Nitrilimines. Rouatbi, F., Mhiri, C., Askri, M., Knorr, M., Rousselin, Y., Kubicki, M. M., Journal of Heterocyclic Chemistry 2017, 54, 1152-1160.
• Synthesis, Characterization and Electrochemistry of Open-Chain Pentapyrroles and Sapphyrins with Highly Electron Withdrawing meso-Tetraaryl substituents. Shan, W., Desbois, N., Blondeau-Patissier, V., Naitana, M. L., Quesneau, V., Rousselin, Y., Gros, C. P., Ou, Z., Kadish, K. M., Chemistry 2017, 23, 12833-12844.
• Straightforward synthesis of bis-tetraazacycloalkanes: towards new potential CXCR4 antagonists? Sok, N., Baglin, I., Basset, C., Fakkor, F., Kohli, E., Rousselin, Y., Bernhard, C., Boschetti, F., Goze, C., Denat, F., RSC Advances 2017, 7, 28291-28297.
• Design of new sensitive α,β-unsaturated carbonyl 1,8-naphtalimide fluorescent probes for thiol bioimaging. Sok, N., Nikolantonaki, M., Guyot, S., Nguyen, T. D., Viaux, A.-S., Bagala, F., Rousselin, Y., Husson, F., Gougeon, R., Saurel, R., Sensors and Actuators B: Chemical 2017, 242, 865-871.
o 2016
• Bis{(4-methylthio)phenylthio}methane as assembling ligand for the construction of Cu(I) and Hg(II) coordination polymers. Crystal structures and topological (AIM) analysis of the bonding. Chaabéne, M., Khatyr, A., Knorr, M., Askri, M., Rousselin, Y., Kubicki, M. M., Inorganica Chimica Acta 2016, 451, 177-186.
• Crystal structure of 4,4-dibromo-1-(3,4-dimethoxyphenyl)-2-azabuta-1,3-diene-1-carbonitrile. Chaabene, M., Khatyr, A., Knorr, M., Askri, M., Rousselin, Y., Kubicki, M. M., Acta Crystallographica Section E Crystallographic Communications 2016, 72, 1167-1170.
• Synthesis of Isoxazole and 1,2,3-Triazole Isoindole Derivatives via Silver- and Copper-Catalyzed 1,3-Dipolar Cycloaddition Reaction. Rammah, M. M., Gati, W., Mtiraoui, H., Rammah Mel, B., Ciamala, K., Knorr, M., Rousselin, Y., Kubicki, M. M., Molecules 2016, 21, 307.
• Synthesis, UV/vis, FT-IR and Mössbauer spectroscopic characterization and molecular structure of the Bis[4-(2-aminoethyl)morpholine](tetrakis(4-metoxyphenyl)porphyrinato) iron(II) complex. Ben Haj Hassen, L., Ezzayani, K., Rousselin, Y., Stern, C., Nasri, H., Schulz, C. E., Journal of Molecular Structure 2016, 1110, 138-142.
• The Stereoselective Self-Assembly of Chiral Metallo-Organic Cryptophanes. Schaly, A., Rousselin, Y., Chambron, J.-C., Aubert, E., Espinosa, E., European Journal of Inorganic Chemistry 2016, 2016, 832-843.
• 1,4-Bis(arylthio)but-2-enes as Assembling Ligands for (Cu2X2)n(X = I, Br;n= 1, 2) Coordination Polymers: Aryl Substitution, Olefin Configuration, and Halide Effects on the Dimensionality, Cluster Size, and Luminescence Properties. Bonnot, A., Knorr, M., Guyon, F., Kubicki, M. M., Rousselin, Y., Strohmann, C., Fortin, D., Harvey, P. D., Crystal Growth & Design 2016, 16, 774-788.
• 1,3-Dipolar cycloaddition of diaryldiazomethanes across N-ethoxy-carbonyl-N-(2,2,2-trichloroethylidene)amine and reactivity of the resulting 2-azabutadienes towards thiolates and cyclic amides. Kinghat, R., Schmitt, G., Ciamala, K., Khatyr, A., Knorr, M., Jacquot-Rousseau, S., Rousselin, Y., Kubicki, M. M., Comptes Rendus Chimie 2016, 19, 319-331.
• Ditopic Macrocyclic Receptors with a 4,7-Diamino-1,10-phenanthroline Fragment for Multimodal Detection of Toxic Metal Ions. Abel, A. S., Mitrofanov, A. Y., Rousselin, Y., Denat, F., Bessmertnykh-Lemeune, A., Averin, A. D., Beletskaya, I. P., ChemPlusChem 2016, 81, 35-39.
• Designing P-Chirogenic 1,2-Diphosphinobenzenes at Both P-Centers Using P(III)-Phosphinites. Bayardon, J., Rousselin, Y., Juge, S., Org Lett 2016, 18, 2930-3.
• Stoichiometry-controlled cycloaddition of nitrilimines with unsymmetrical exocyclic dienones: microwave-assisted synthesis of novel mono- and dispiropyrazoline derivatives. Gazzeh, H., Boudriga, S., Askri, M., Khatyr, A., Knorr, M., Strohmann, C., Golz, C., Rousselin, Y., Kubicki, M. M., RSC Adv. 2016, 6, 49868-49875.
• Reinforced cyclam derivatives functionalized on the bridging unit. Sok, N., Baglin, I., Rousselin, Y., Boschetti, F., Bernhard, C., Goze, C., Denat, F., New J. Chem. 2016, 40, 5829-5834.
• Synthesis, spectroscopic, and X-ray structural study of aqua-bis(thymine-N1,N4)-ethylenediamine copper(II)dihydrate [Cu(Thy)2(en)(H2O)].2H2O. Mokhtari, R., Adkhis, A., Berradj, O., Michaud, F., Rousselin, Y., Top, S., Inorganic and Nano-Metal Chemistry 2016, 47, 841-844.
o 2015
• Crystal structure of diaqua[5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinato-κ4N]iron(III) diaqua(18-crown-6)potassium bis(trifluoromethanesulfonate)–18-crown-6 (1/2). Ben Haj Hassen, L., Denden, Z., Rousselin, Y., Nasri, H., Acta Crystallographica Section E Crystallographic Communications 2015, 71, m215-m216.
• Modular P-Chirogenic Phosphine-Sulfide Ligands: Clear Evidence for Both Electronic Effect andP-Chirality Driving Enantioselectivity in Palladium-Catalyzed Allylations. Bayardon, J., Maronnat, M., Langlois, A., Rousselin, Y., Harvey, P. D., Jugé, S., Organometallics 2015, 34, 4340-4358.
• Conformational and structural studies of N-methylacetohydroxamic acid and of its mono- and bis-chelated uranium(VI) complexes. Brandes, S., Sornosa-Ten, A., Rousselin, Y., Lagrelette, M., Stern, C., Moncomble, A., Cornard, J. P., Meyer, M., J Inorg Biochem 2015.
• Regio- and Stereoselective Synthesis of Spiropyrrolizidines and Piperazines through Azomethine Ylide Cycloaddition Reaction. Haddad, S., Boudriga, S., Porzio, F., Soldera, A., Askri, M., Knorr, M., Rousselin, Y., Kubicki, M. M., Golz, C., Strohmann, C., J Org Chem 2015, 80, 9064-75.
• Crystal structure of (R)-6-fluoro-2-[(S)-oxiran-2-yl]chroman. Rousselin, Y., Laureano, H., Clavel, A., Acta Crystallographica Section E 2015, 71, o552-o553.
• Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular CuIS and CuIS Clusters to Luminescent Copper(I) Coordination Polymers. Knorr, M., Bonnot, A., Lapprand, A., Khatyr, A., Strohmann, C., Kubicki, M. M., Rousselin, Y., Harvey, P. D., Inorg Chem 2015, 54, 4076-4093.
• Efficient Synthesis of (P-Chirogenic) o-Boronated Phosphines from sec-Phosphine Boranes. Bayardon, J., Bernard, J., Remond, E., Rousselin, Y., Malacea-Kabbara, R., Juge, S., Org Lett 2015, 17, 1216-9.
• Synthesis and Structural Study of Tetravalent (Zr4+, Hf4+, Ce4+, Th4+, U4+) Metal Complexes with Cyclic Hydroxamic Acids. Jewula, P., Berthet, J.-C., Chambron, J.-C., Rousselin, Y., Thuéry, P., Meyer, M., European Journal of Inorganic Chemistry 2015, 1529-1541.
• Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt). Mohamed, A. S., Jourdain, I., Knorr, M., Rousselin, Y., Kubicki, M. M., Acta Crystallographica Section E Crystallographic Communications 2015, 71, 241-243.
• Synthesis of highly substituted spiropyrrolidines via 1, 3-dipolar cycloaddition reaction of N-metalated azomethine ylides. A new access to spiropyrroline derivatives. Mhiri, C., Rouatbi, F., Ciamala, K., Monnier-Jobé, K., Khatyr, A., Rousselin, Y., Kubicki, M., Mediterranean Journal of Chemistry 2015, 4, 30-50.
• A strategic approach to the synthesis of functionalized spirooxindole pyrrolidine derivatives: in vitro antibacterial, antifungal, antimalarial and antitubercular studies. Haddad, S.; Boudriga, S.; Akhaja, T. N.; Raval, J. P.; Porzio, F.; Soldera, A.; Askri, M.; Knorr, M.; Rousselin, Y.; Kubicki, M. M.; Rajani, D., New Journal of Chemistry 2015, 39 (1), 520-528.
o 2014
• Di-aqua-[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyrinato-kappa(4) N]iron(III) tri-fluoro-methane-sulfonate-4-hy-droxy-3-meth-oxy-benzaldehyde-water (1/1/2). Ben Haj Hassen, L., Ezzayani, K., Rousselin, Y., Nasri, H., Acta Crystallogr Sect E Struct Rep Online 2014, 70, m296-7.
• Efficient Synthesis of 1,4,7-Triazacyclononane and 1,4,7-Triazacyclononane-Based Bifunctional Chelators for Bioconjugation. Désogère, P., Rousselin, Y., Poty, S., Bernhard, C., Goze, C., Boschetti, F., Denat, F., European Journal of Organic Chemistry 2014, 7831-7838.
• Synthesis of novel dispiropyrrolothiazoles by three-component 1,3-dipolar cycloaddition and evaluation of their antimycobacterial activity. Haddad, S., Boudriga, S., Porzio, F., Soldera, A., Askri, M., Sriram, D., Yogeeswari, P., Knorr, M., Rousselin, Y., Kubicki, M. M., RSC Advances 2014, 4, 59462-59471.
• 1,3-Dipolar Cycloaddition Reactions of Indan-1-one Enamines across Arylnitrile Oxides Leading to Novel Cyclic Isoxazoline Derivatives. Jelizi, H., Wannassi, N., El Baker Rammah, M., Ciamala, K., Knorr, M., Rousselin, Y., Kubicki, M. M., Strohmann, C., Enescu, M., Journal of Heterocyclic Chemistry 2014, 51, 383-391.
• A 4-tert-butylcalix[4]arene tetrahydroxamate podand based on the 1-oxypiperidine-2-one (1,2-PIPO-) chelate. Self-assembly into a supramolecular ionophore driven by coordination of tetravalent zirconium or hafnium(iv). Jewula, P., Chambron, J.-C., Penouilh, M.-J., Rousselin, Y., Meyer, M., RSC Advances 2014, 4, 22743-22754.
• Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]. Kinghat, R., Knorr, M., Rousselin, Y., Kubicki, M. M., Acta Crystallographica Section E 2014, 70, 547-549.
• Copper(I) Halides (X = Br, I) Coordinated to Bis(arylthio)methane Ligands: Aryl Substitution and Halide Effects on the Dimensionality, Cluster Size, and Luminescence Properties of the Coordination Polymers. Knorr, M., Khatyr, A., Dini Aleo, A., El Yaagoubi, A., Strohmann, C., Kubicki, M. M., Rousselin, Y., Aly, S. M., Fortin, D., Lapprand, A., Harvey, P. D., Crystal Growth & Design 2014, 5373-5387.
• Supramolecular Architectures Based on Phosphonic Acid Diesters. Lemeune, A., Mitrofanov, A. Y., Rousselin, Y., Stern, C., Guilard, R., Enakieva, Y. Y., Gorbunova, Y. G., Nefedov, S. E., Phosphorus, Sulfur, and Silicon and the Related Elements 2014, 831-836.
• Structural and Electrochemical Studies of Copper(I) Complexes with Diethoxyphosphoryl-1,10-phenanthrolines. Mitrofanov, A., Manowong, M., Rousselin, Y., Brandès, S., Guilard, R., Bessmertnykh-Lemeune, A., Chen, P., Kadish, K. M., Goulioukina, N., Beletskaya, I., European Journal of Inorganic Chemistry 2014, 2014, 3370-3386.
• Thioetherification of chloroheteroarenes: a binuclear catalyst promotes wide scope and high functional-group tolerance. Platon, M., Wijaya, N., Rampazzi, V., Cui, L., Rousselin, Y., Saeys, M., Hierso, J. C., Chemistry 2014, 20, 12584-94.
• Towards sensory Langmuir monolayers consisting of macrocyclic pentaaminoanthraquinone. Ranyuk, E., Ermakova, E. V., Bovigny, L., Meyer, M., Bessmertnykh-Lemeune, A., Guilard, R., Rousselin, Y., Tsivadze, A. Y., Arslanov, V. V., New Journal of Chemistry 2014, 38, 317-329.
o 2013
• A triclinic polymorph of (-)-(S)-N-benzyl-2-[(R)-6-fluorochroman-2-yl]-2-hydroxyethanaminium bromide. Rousselin, Y., H. Laureano, A. Clavel, Acta Cryst. Sect. E, 2013, 69(12), o1794-o1795.
• 1,3-Dipolar Cycloaddition Reactions of Indan-1-one Enamines across Arylnitrile Oxides Leading to Novel Cyclic Isoxazoline Derivatives. Jelizi, H.; Wannassi, N.; El Baker Rammah, M.; Ciamala, K.; Knorr, M.; Rousselin, Y.; Kubicki, M. M.; Strohmann, C.; Enescu, Journal of Heterocyclic Chemistry, 2013, 69, o1794-o1795.
• Etude de la réaction de cycloaddition dipolaire-1,3 des ylures d'azométhine N-métallés sur les 3-arylidiènes-1-phényl-pyrrolidine-2,5-diones Haddad, S., Jalloul, I., Boudriga, S., Askri, M., Knorr, M., Rousselin, Y. & Kubicki, M. M. J. Soc. Chim. Tunisie 2013, 15, 1-8.
• (R)-(-)-quinuclidin-3-ol Rousselin, Y.; Clavel, A.; Bonnaventure, I., Acta Cryst. Sect. E 2013, 69 (11), o1672-o1672.
• Cluster-Containing Coordination Polymers Built Upon (Cu2I2S2)m Units (m = 2, 3) and ArSCH2C≡CCH2SAr Ligands: Is the Cluster Size Dependent Upon Steric Hindrance or Ligand Rigidity? S. M. Aly, A. Pam, A. Khatyr, M. Knorr, Y. Rousselin, M. M. Kubicki, J. O. Bauer, C. Strohmann, P. D. Harvey, J. Inorg. Organomet. P., 2013, 24, 190-200.
• Boron Functionalization of BODIPY by various Alcohols and Phenols B. Brizet, C. Bernhard, Y. Rousselin, Y. Volkova, P. D. Harvey, C. Goze, F. Denat, Org. & Biomol. Chem., 2013, 11, 7729-37.
• Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect A. Lapprand, A. Bonnot, M. Knorr, Y. Rousselin, M. M. Kubicki, D. Fortin, P. D. Harvey, Chem. Comm., 2013, 49, 8848-8850.
• Luminescent P-Chirogenic Copper Clusters A. Lapprand, M. Dutartre, N. Khiri, E. Levert, D. Fortin, Y. Rousselin, A. Soldera, S. Jugé, P. D. Harvey, Inorg. Chem., 2013, 52, 7958-7967.
• O-(Hydroxyalkyl)phenyl P-Chirogenic Phosphines as Functional Chiral Lewis Bases Remond, E; Bayardon, J.; Takizawa, S.; Rousselin, Y.; Sasai, H.; Juge, S. Org. Lett., 2013, 15, 1870-3.
• P-Chirogenic Phosphines Supported by Calix[4]arene: New Insight into Palladium-Catalyzed Asymmetric Allylic Substitution Khiri-Meribout, N.; Bertrand, E.; Bayardon, J.; Eymin, M.-J.; Rousselin, Y.; Cattey, H.; Fortin, D.; Harvey, P. D.; Jugé, S. Organometallics, 2013, 32, 2827-2839.
• Remarkable Inertness of Copper(II) Chelates of Cyclen-Based Macrobicycles with Two trans-N-Acetate Arms Esteves, C. V.; Lamosa, P.; Delgado, R.; Costa, J.;Desogere, P.; Rousselin, Y.; Goze, C.; Denat, F. Inorg Chem, 2013, 52, 5138-53.
• Selectively Functionalized Constrained Polyazamacrocycles: Building Blocks for Multifunctional Chelating Agents Désogère, P. ; Bernhard, C. ; Goze, C. ; Penouilh, M.-J. ; Rousselin, Y. ; Denat, F. Eur. J. Org. Chem. 2013, 8, 1538-1545.
o 2012
• (S,S,S,S)-Nebivolol hydro­chloride hemihydrate Rousselin, Y., A. Bruel, and A. Clavel,. Acta Cryst. Sect. E 2012, 68, 3352-3352.
• Diethyl 2,2'-(1,4-phenylenedioxy)diacetate Husson J. Husson; Knorr, M.; Rousselin, Y.; Kubicki, M. M. Acta Cryst. Sect. E 2012, 68, o2422.
• Stereoselective Synthesis of o-Bromo (or Iodo)aryl P-Chirogenic Phosphines Based on Aryne Chemistry Bayardon, J.; Laureano, H.; Diemer, V.; Dutartre, M.; Das, U.; Rousselin, Y.; Henry, J.-C.; Colobert, F.; Leroux, F. R.; Jugé, S. J. Org. Chem. 2012, 77, 5759-5769.
• DOTAGA–Anhydride: A Valuable Building Block for the Preparation of DOTA-Like Chelating Agents Bernhard, C.; Moreau, M.; Lhenry, D.; Goze, C.; Boschetti, F.; Rousselin, Y.; Brunotte, F.; Denat, F. Chem. Eur. J. 2012, 18, 7834-7841.
• 1,3-Dipolar Cycloaddition of Ethyl Diazoacetate with (E)-3-Arylidenechroman-4-ones. A New Access to Spirocyclopropane Derivatives Wannassi, N.; Jelizi, H.; Rammah, M. E. B.; Ciamala, K.; Knorr, M.; Monnier-Jobé, K.; Rousselin, Y.; Kubicki, M. M.; Strohmann, C. Heterocycles 2012, 85, 835-849
• Identifying three-way DNA junction-specific small-molecules, Vuong, S.; Stefan, L.; Lejault, P.; Rousselin, Y.; Denat, F.; Monchaud, D. Biochimie 2012, 94, 442 - 450.
• Synthesis, crystallographic and electrochemical study of ethynyl[2.2]paracyclophane-derived cobalt metallatetrahedranes, Clément, S.; Guyard, L.; Khatyr, A.; Knorr, M.; Rousselin, Y.; Kubicki, M. M.; Mugnier, Y.; Richeter, S.; Gerbier, P.; Strohmann, C. J. Organomet. Chem. 2012, 699, 56-66.
o 2011
• Design and Photophysical Properties of Zinc(II) Porphyrin-Containing Dendrons Linked to a Central Artificial Special Pair, Brégier, F.; Aly, S. M.; Gros, C. P.; Barbe, J.-M.; Rousselin, Y.; Harvey, P. D. Chem. Eur. J. 2011, 17, 14643-14662.
• Effect of t-BuS vs. n-BuS on the topology, CuCu distances and luminescence properties of 2D Cu4I4/RS(CH2)4SR metal-organic frameworks, Knorr, M.; Guyon, F.; Kubicki, M. M.; Rousselin, Y.; Aly, S. M.; Harvey, P. D. New J. Chem. 2011, 35, 1184-1188.
• Selective CO2 Adsorption by a Triazacyclononane-Bridged Microporous Metal–Organic Framework, Ortiz, G.; Brandès, S.; Rousselin, Y.; Guilard, R. Chem. Eur. J. 2011, 17, 6689-6695.
• Synthesis, structure and coordination properties of three cyclam-based ligands bearing one scorpionate arm, Kannappan, R.; Rousselin, Y.; Jabri, R. Z.; Goze, C.; Brandès, S.; Guilard, R.; Zrineh, A.; Denat, F. Inorg. Chim. Acta 2011, 373, 150-158.
o 2010
• Reactivity of Pd3(dppm)3(CO)n+ and Pd3(dppm)3(CO)(RCCR)n+ (n = 0, +1, +2) Towards F−. Evidence of Reactive Intermediates and X-Ray Structure of [Pd3(dppm)3(MeO2CC≡CCO2Me)(F)]PF6, Fournier, S.; Cugnet, C.; Vallat, A.; Devillers, C.; Rousselin, Y.; Kubicki, M.; Lucas, D.; Mugnier, Y.; Harvey, P. J. Clust. Sci. 2010, 21, 837-856.
• Regio- and Stereoselective 1,3-Dipolar Cycloaddition of C-Aryl-N-phenylnitrones over (E)-Arylidene-(2H)-indan-1-ones: Synthesis of Highly Substituted Novel Spiro-isoxazolidines, Wannassi, N.; Rammah, M. M.; Boudriga, S.; Rammah, M. E. B.; Monnier-Jobé, K.; Ciamala, K.; Knorr, M.; Enescu, M.; Rousselin, Y.; Kubicki, M. M. Heterocycles 2010, 81, 2749 - 2762.
• First bodipy–DOTA derivatives as probes for bimodal imaging, Bernhard, C.; Goze, C.; Rousselin, Y.; Denat, F. Chem. Comm. 2010, 46, 8267-8269.
• Enantioselective Hydrogenation Catalysis Aided by a σ-Bonded Calix[4]arene to a P-Chirogenic Aminophosphane Phosphinite Rhodium Complex, Khiri, N. ; Bertrand, E.; Ondel-Eymin, M.-J. ; Rousselin, Y.; Bayardon, J. ; Harvey, P. D.; Jugé, S. Organometallics 2010, 29, 3622-3631.
• Reactivity of CuI and CuBr toward Et2S: a Reinvestigation on the Self-Assembly of Luminescent Copper(I) Coordination Polymers, Knorr, M.; Pam, A.; Khatyr, A.; Strohmann, C.; Kubicki, M. M.; Rousselin, Y.; Aly, S. M.; Fortin, D.; Harvey, P. D. Inorganic Chem. 2010, 49, 5834-5844.
• Efficient Synthesis of New C-Functionalized Macrocyclic Polyamines, Rousselin, Y.; Sok, N.; Boschetti, F.; Guilard, R.; Denat, F. Eur. J. Org. Chem. 2010, 1688-1693.
• Exploring the redox reactivity of magnesium porphine. Insight into the origins of electropolymerisation, Devillers, C. H.; Lucas, D.; Dime, A. K. D.; Rousselin, Y.; Mugnier, Y. Dalton Trans 2010, 39, 1-8.
o 2009
• 1,8-Bis[3-(triethoxysilyl)propyl]-1,8-diazoniatricyclo[9.3.1.14,8]hexadecane diiodide, Rousselin, Y.; Denat, F.; Lebeau, B.; Walcarius, A. Acta Cryst. Sect. E, 2009, 65, o2531.
• The Cu(II) complex of a C-lipophilized 13aneN4 macrocycle with an additional protonable amino group as micellar anion receptor, Denat, F.; Diaz-Fernandez, Y. A.; Pallavicini, P.; Pasotti, L.; Rousselin, Y.; Sok, N. Dalton Trans, 2009, 6751 - 6758.
• Synthesis of meso-Polyphosphorylporphyrins and Example of Self-Assembling, Enakieva, Y. Y.; Bessmertnykh, A. G.; Gorbunova, Y. G.; Stern, C.; Rousselin, Y.; Tsivadze, A. Y.; Guilard, R. Org. Lett., 2009, 11, 3842-3845.
• Multiarm Cyclam-Grafted Mesoporous Silica: A Strategy to Improve the Chemical Stability of Silica Materials Functionalized with Amine Ligands, Etienne, M., Goubert-Renaudin, S.; Rousselin, Y., Marichal, C., Denat, F., Lebeau, B., Walcarius, A., Langmuir, 2009, 25, 3137-3145.
• Cyclam-functionalized silica-modified electrodes for selective determination of Cu(II), Goubert-Renaudin S., Etienne M., Rousselin Y., Denat F., Lebeau B., Walcarius A., Electroanalysis, 2009, 21, 280-289.
o 2008
• Micelles as Containers for Self-Assembled Nanodevices: A Fluorescent Sensor for Lipophilicity, G. Chirico, M. Collini, L. D'Alfonso, F. Denat, Y. A. Diaz-Fernandez, L. Pasotti, Y. Rousselin, N. Sok, P. Pallavicini, ChemPhysChem, 2008, 9, 1729-1737.

èOral communications

  1. Un nouveau précurseur pour la synthèse de polyamines cycliques, Journées des Ecoles Doctorales Carnot et Pasteur (Besançon, 2006).
  2. New synthetic tool for the preparation of macrocyclic polyamines, 2nd workshop Germany-France (Dijon, 2006).
  3. Nouvelles méthodes de C-fonctionnalisation de polyamines cycliques, Journées des Ecoles Doctorales Carnot et Pasteur (Dijon, 2007).
  4. Efficient tools for the synthesis of cyclen and cyclam derivatives, F. Denat, F. Boschetti, F. Chaux, Y. Rousselin, R. Guilard, 2nd ISMSC (Salice Terme, Italie, 2007).
  5. A fluorescent micellar lipophilicity-meter for carboxylates, VIII Congresso Nazionale Di Chimica Supramoleculare (Trieste, Italie, 2007).

èPoster communications

  1. Nouvelle méthode de synthèse de monooxotétraazacycloalcanes, Journées des Ecoles Doctorales Carnot et Pasteur (Dijon, 2005).
  2. Un nouveau précurseur pour la synthèse de polyamines cycliques, Y. Rousselin, F. Denat, R. Guilard, 1ères journées du GPOL (Landeda, 2006).
  3. New route for the C-functionalisation of macrocyclic polyamines, Y. Rousselin, F. Denat, F. Boschetti, R. Guilard, 2nd ISMSC (Salice Terme, Italie, 2007).
  4. A fluorescent micellar lipophilicity-meter for carboxylates, 2nd ISMSC (Salice Terme, Italie, 2007).
  5. One-pot synthesis of Cyclam-functionalized MCM-41 and MCM-48 mesoporous silicas for heavy-metal Remediation,
  6. Cu(II) detection at a carbon paste electrode modified by amorphous and ordered cyclam-functionalized mesoporous silica,
  7. Structural Investigation of Ordered Mesoporous Silicas Functionalized by Direct Synthesis with Cyclam Derivatives, NANO-V (Vancouver, British Columbia, Canada, 2008).
  8. Synthesis of new multifunctional chelating agents based on macrocyclic tetraamines,