EMMD - Electrochemistry, Molecular Materials and Devices

EMMD (Electrochemistry, Molecular Materials and Devices) research activities are devoted to molecular materials, from molecules to materials and from materials to devices. Electrochemical techniques are used to synthesize, to immobilize and to detect chemical or biological species. The synthetic aspect relates to the synthesis and functionalization of macrocycles (porphyrins, phthalocyanines…) and polymers. The analytical aspect 1) exploits the redox properties of compounds or sensitive layers (biomaterials, conducting polymers, charge-transfer complexes, …) for the characterization and the detection of biomolecules or chemical pollutants in sensor devices; 2) to apprehend reaction mechanism of molecular processes. Our projects are focused on applications in the fields of environment, health and food industry.

BAYARDON Jérôme Voir la fiche profil en français Français (FR)

image-profil
  • BAYARDON Jérôme
  • Statut : Associate Professor
  • Team : OCS
  • Function : Researchers
  • Tags : Catalysis, Heterochemistry, Synthetic chemistry
  • ORCID : 0000-0003-2165-1315
  • Address :

    ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
    Bât. MIRANDE - Aile B - Bureau 222
    9 Avenue Alain Savary
    21000 Dijon – France

  • Tél : +33 380 396 102
  • Jerome.Bayardon@u-bourgogne.fr

After obtention of my PhD in organic and organometallic chemistry as well as in asymmetric catalysis at the University of Lyon in 2004 under the supervision of Pr. Denis Sinou, I worked for one year as lecture-assistant in the same University. Then I worked for one year as a postdoctoral research fellow on the development of a new media for asymmetric catalysis in the group of Professor Börner at the Leibniz Institüt für Organische Katalyse in Rostock (Germany). In 2006, I joined the team of Pr. Sylvain Jugé as an assistant professor at the Université of Bourgogne-Franche Comté where I obtained my HDR in 2016. 

My current interests are the synthesis of (P-chirogenic) phosphorus compounds for (asymmetric) catalysis with transition metals and organocatalysis.

34 articles, 5 patents (3 with international extension), 3 sealed folds (envelope Soleau), 2 book chapters

Main publications:
1) Efficient sythesis of quaternary and P-stereogenic phosphonium triflates
E. Rémond, A. Tessier, F. R. Leroux, J. Bayardon, S. Jugé, Org. Lett. 2010, 12, 1568-1571
2) Stereoselective synthesis of o-bromo (or iodo)aryl P-chirogenic phosphines based on aryne chemistry
J. Bayardon, H. Laureano, V. Diemer, M. Dutartre, U. Das, Y. Rousselin, J. -C. Henry, F. Colobert, F. R. Leroux, S. Jugé, J. Org. Chem. 2012, 77, 5759-5769
3) Stereoselective synthesis of unsaturated and functionalized L-NHBoc amino acids, using Wittig reaction under mild phase transfer conditions
E. Rémond, J. Bayardon, M. -J. Ondel-Eymin, S. Jugé, J. Org. Chem. 2012, 77, 7579-7587
4) o-(Hydroxylalkyl)phenyl P-Chirogenic phosphines as functional chiral Lewis bases
E. Rémond, J. Bayardon, S. Takisawa, Y. Rousselin, H. Sasai, S. Jugé, Org. Lett. 2013, 15, 1870-1873
5) P-chirogenic organocatalysts: application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines
S. Takizawa, E. Rémond, F. A. Arteaga, Y. Yoshida, V. Sridharan, J. Bayardon, S. Jugé, H. Sasai, Chem. Commun.2013, 48, 8392-8394
6) Efficient synthesis of (P-chirogenic) o-boronated phosphines from sec-phosphine boranes
J. Bayardon, J. Bernard, E. Rémond, Y. Rousselin, R. Malacea-Kabbara, S. Juge, Org. Lett. 2015, 17, 1216-1219
7) Modular P-chirogenic phosphine-sulfide-ligands: clear evidence for both electronic effect and P-chirality driving enantioselectivity in Pd-catalyzed allylations
J. Bayardon, M. Maronnat, A. Langlois, Y. Rousselin, P. D. Harvey, S. Juge, Organometallics2015, 34, 4340-4358
8) Designing P-chirogenic 1,2-diphosphinobenzenes at both P6centers using P(III)-phosphinites
J. Bayardon, Y. Rousselin, S. Jugé, Org. Lett. 2016, 18, 2930-2933
9) Applications and setreoselective syntheses of P-chirogenic phosphorus compounds
M. Dutartre, J. Bayardon, S. Jugé, Chem. Soc. Rev. 2016, 45, 5771-5794

21 oral communications and 39 poster in 39 national and international congresses. 

- First and second year of bachelor’s degree : general and organic chemistry
- Professional bachelor's degree in Control-Process-Quality for the Pharmaceutical, Cosmetological and health Industries: Co-lead, organic chemistry, spectroscopic and chromatographic methods 

Organic chemistry, Phosphorus chemistry, asymmetric synthesis and catalysis.