LEMEUNE Alla Voir la fiche profil en français Français (FR)

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  • LEMEUNE Alla
  • Statut : Researcher (CR-HDR)
  • Team : PD2A
  • Function : Researchers
  • Tags : Catalysis, Molecular materials, Sensors
  • Address :

    ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
    Bât. MIRANDE - Aille B - Bureau R21
    9 Avenue Alain Savary
    21000 Dijon – France

  • Tél : +33 380 396 126
  • Alla.Lemeune@u-bourgogne.fr

Alla Bessmertnykh-Lemeune is CNRS Senior Researcher (CR-HC) at the Institute of Molecular Chemistry of Burgundy University (ICMUB). She graduated from Lomonosov Moscow State University in 1985. After PhD thesis with Prof. Yu. S. Shabarov in Moscow (1988), she joined the laboratory of Prof. I. Beletskaya at Lomonosov Moscow State University. In 2000 she moved in France and after post-doctoral fellowships with Prof. R. Guilard, Dr. G. Bertrand and Prof. F. Hénin, she was appointed Development responsible at Finorga/Novasep. She received her habilitation in Organic Chemistry in 2002 and got a tenure position at CNRS in 2005.  

Our research activity related to sustainable chemistry and protection of the environment is an integral part of one of the principal axes in ICMUB (UMR CNRS 6302) program. The studies are focused on the chemistry of nitrogen ligands and their complexes and consist of three main topics:

• development of chemosensors and sensing materials for selective detection of harmful and environmentally-relevant metal ions;
• biomimetic studies of supramolecular metal complexes and coordination polymers, aiming at a deeper comprehension of natural processes and development of advanced photoactive and thermochromic materials;
• preparation of porous organic-inorganic materials for sustainable catalytic reactions.

Our "bottom up" strategy is composed of three consecutive steps:

1) synthesis of sophisticated nitrogen ligands functionalized by phosphonate and carboxylate groups;
2) investigation of their coordination properties;
3) design and preparation of functional organic-inorganic materials. We are developing rational synthetic approaches to functionalized nitrogen ligands, studying their unusual coordination properties and exploring different routes for their immobilization such as self-assembly, incorporation into crystalline metal-organic frameworks and amorphous metal oxide matrices, grafting onto a surface of metal oxides and preparation of film materials by using SAM and LB techniques.

This is a joint project (2011-2019) with six Russian groups (Pr. V. Arslanov, Dr. A. Averin, Pr. I. Beletskaya, Dr. A. Cheprakov, Dr. Yu. Gorbunova, Pr. S. Nefedov) in the frames of International Associated Laboratory of CNRS «LAboratory of Macrocyclic systems and RElated Materials» (LAMREM).  

1.         Abdulaeva I. A., Birin K. P., Gorbunova Yu. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A., Guilard R., Gorbunova Yu. G., Tsivadze A. Yu., Post-synthetic methods for functionalization of imidazole-fused porphyrins, J. Porphyrins Phthalocyanines, 22, 2018, DOI: 10.1142/S1088424618500475.

2.         Feuchter H., Ortiz G., Rousselin Y., Bessmertnykh-Lemeune A., Brandès S., Cadmium Metal–Organic Frameworks Based on Ditopic Triazamacrocyclic Linkers: Unusual Structural Features and Selective CO2 Capture, Cryst. Growth Des.,17(7), 2017,3665-3676.

3.         Mitrofanov A., Brandès S., Herbst F., Rigolet S., Bessmertnykh-Lemeune A., Beletskaya I., Immobilization of copper complexes with (1,10-phenanthrolinyl)phosphonates on titania supports for sustainable catalysis, J. Mater. Chem. A, 5(24), 2017, 12216-12235.

4.         Enakieva Yu. Yu., Volostnykh M. V., Nefedov S. E., Kirakosyan G. A., Gorbunova Yu. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A., Stern C., Guilard R., Gallium(III) and indium(III) complexes with meso-monophosphorylated porphyrins: synthesis and structure. The first example of dimers formed by self-assembly of meso-porphyrinyl phosphonic acid monoester, Inorg. Chem., 56 (5), 2017, 3055–3070.

5.         Bessmertnykh-Lemeune A., Guilard R., Stern C., Enakieva Yu. Yu., Gorbunova Yu. G., Tsivadze A. Yu., Nefedov S. E., Biomimetic Studies of Porphyrin Self-Assembled Systems, In: Supramolecular Systems: Chemistry, Types and Applications. Chapter 4. Nova Science Publishers, Inc., 2016, p 213-278.

6.         Enakieva Yu. Yu., Michalak, J., Abdulaeva I. A., Volostnykh M. V., Stern C., Guilard R., Bessmertnykh-Lemeune A., Gorbunova Yu. G., Tsivadze A. Yu., Kadish, K. M., General and Scalable Approach to A2B- and A2BC-Type Porphyrin Phosphonate Diesters,Eur. J. Org. Chem., (28), 2016, 4881–4892.

7.         Mitrofanov A.,Rousselin Y.,Guilard R.,Brandès S.,Bessmertnykh-Lemeune A. G.,Uvarova M. A., Nefedov S. E., Copper(II) Complexes with Phosphorylated 1,10-Phenanthrolines: from Molecules to Infinite Supramolecular Arrays, New J Chem, 40(7), 2016, 5896-5905.

8.         Ermakova E., Raitman O., Shokurov A., Kalinina M., Selector S., Arslanov V., Tsivadze A., Meyer M., Bessmertnykh-Lemeune A., Guilard R., Metal-responsive interdigitated bilayer for selective quantification of mercury(II) traces by surface plasmon resonance, Analyst,141(6), 2016, 1912-1927.

9.         Abdulaeva I. A., Birin K. P., Michalak, J., Romieu A., Stern C., Bessmertnykh-Lemeune A., Guilard, R., Gorbunova Yu. G., Tsivadze A. Yu., On the synthesis of functionalized porphyrins and porphyrin conjugates via aminoporphyrin, New. J. Chem., 40(7), 2016, 5758-5774.

10.       Abel A. S., Mitrofanov A. Yu., Rousselin Y., Denat F., Bessmertnykh-Lemeune A., Averin A. D., Beletskaya I. P., Ditopic Macrocyclic Receptors with 4,7-diamino-1,10-phenanthro-line fragment for multimodal detection of toxic metal ions, ChemPlusChem, 81(1), 2016,35-39.

11.       Birin K. P., Gorbunova Yu. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A. G., Guilard, R., New Insights into the Synthesis and the Solution Behaviour of meso-Aryloxy- and Alkoxy-Substituted Porphyrins, Eur. J. Org. Chem., (25), 2015, 5610-5619.

12.       Arslanov V., Ermakova E., Michalak J., Bessmertnykh-Lemeune A., Meyer M., Raitman O., Vysotskij V., Guilard R., Tsivadze A., Design and Evaluation of Sensory Systems Based on Amphiphilic Anthraquinones, Colloids and Surf., A, 483, 2015,193–203.

13.       Mitrofanov A. Yu.,Bessmertnykh-Lemeune A. G.,Beletskaya I. P., Cu(I) Complexes with Diethoxyphosphoryl-1,10-phenanthrolines in Catalysis of C–C and C–heteroatom Bond Formation, Inorg. Chim. Acta, 431, 2015, 297-301.

14.       Fang Y., Gorbunova Y. G., Chen P., Jiang X.,Manowong M.,Sinelshchikova A. A., Enakieva Y. Y.,Martynov A. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A.,Stern C., Guilard R., Kadish K. M., Electrochemical and Spectroelectrochemical Studies of Diphosphorylated Metalloporphyrins. Generation of A Phlorin Anion Product, Inorg. Chem., 54(7), 2015, 3501-3512.

15.       LemeuneA., Mitrofanov A., Rousselin Y., Stern C., Guilard R.,Enakieva Yu. Yu., Gorbunova Yu. G., Nefedov S. E., Supramolecular Architectures Based on Phosphonic Acid Diesters, Phosphorus, Sulfur, Silicon Rel. Elem., 190, 2015, 831-836.

16.       Makukhin N. N. ,Goulioukina N. S.,Bessmertnykh-Lemeune A., Brandès S.,Guilard R.,Beletskaya I. P., Exploiting Palladium Catalyzed Cross-coupling for the Synthesis of 2-Aryl Substituted 1–Aminocyclopropylphos-phonates, Synthesis,47, 2015, 279-288.

17.       Uvarova M. A., Sinelshchikova A. A., Golubnichaya M. A., Nefedov S. E., Enakieva Yu. Yu., Gorbunova Yu. G., Tsivadze A. Yu., Stern C., Bessmertnykh-Lemeune A., Guilard R., Supramolecular Assembly of Organophosphonate Diesters using Paddle-wheel Complexes: First Examples in Pporphyrin Series, Crystal Growth & Design, 14(11), 2014, 5976-5984.

18.       Zubatyuk R., Sinelshchikova A. A., Enakieva Y. Y., Gorbunova Y. G., Tsivadze A. Y., Nefedov S. E., Bessmertnykh-Lemeune A., Guilard R., Shishkin O., Insights into Crystal Packing of Phosphorylporphyrins Based on Topology on Intermolecular Interaction Energies, CrystEngComm, 16(45), 2014, 10428-10438.

19.       Mitrofanov A.,Manowong M.,Rousselin Y.,Brandès S.,Guilard R.,Bessmertnykh-Lemeune A.,Chen P.,Kadish K. M.,Goulioukina N.,Beletskaya I., Structural and Electrochemical Studies of Copper(I) Complexes with Diethoxyphosphoryl-1,10-phenanthrolines, Eur. J. Inorg. Chem., 21, 2014, 3370-3386.

20.        Stern C., Bessmertnykh-Lemeune A., Gorbunova Yu. G., Tsivadze A., Guilard R., Effect of the Anchoring Group in Porphyrin Sensitizers: Phosphonate versus Carboxylate linkages, Turk. J. Chem., 38, 2014, 980-993.

21.       Bessmertnykh-Lemeune A., Stern C., Gorbunova Yu. G., Tsivadze A., Guilard R., Survey of Synthetic Routes Towards Phosphorus Substituted Porphyrins, Macroheterocycles, 7(2), 2014, 122-132.

22.       Michalak J., Birin K., Muniappan S., Ranyuk E., Gorbunova Yu., Tsivadze A., Bessmertnykh-Lemeune A., Stern C., Bessmertnykh-Lemeune A., Guilard R., Synthesis of Porphyrin-bis(polyazamacrocycle) Triads via Suzuki Coupling Reaction, J. Porphyrins Phthalocyanines, 18(1-2), 2014, 35-48.

23.       Ranyuk E., Ermakova E. V., Bovigny L, Meyer M., Bessmertnykh-Lemeune A., Guilard R., Rousselin Y, Tsivadze A. Arslanov V. V., Towards Sensory Langmuir Monolayers Consisting of Macrocyclic Pentaaminoanthraquinone, New J. Chem., 38(1), 2014, 317-329.

24.       Uglov A. N., Bessmertnykh-Lemeune A. G., Guilard R., Averin A. D., Beletskaya I. P., Optical Methods for Detection of Heavy Metal Ions. Russ. Chem. Rev., 83(3), 2014, 196-224.

25.       Uglov A. N., Zubrienko G. A., Abel A. S., Averin A. D., Maloshitskaya O. A., Bessmertnykh-Lemeune A. G., Denat F., Beletskaya, I. P., Synthesis of Macrobicycles Comprising 2,7-Diaminonaphthalene Moiety via Palladium-catalyzed Amination Reaction, Heterocycles, 88(2), 2014, 1213-1231.

26.       Fang Y., Kadish K., Chen P., Gorbunova Yu., Enakieva Yu., Tsivadze A., Bessmertnykh-Lemeune A., Guilard R., Electrochemical and Spectroelectrochemical Studies of phosphorylated Zn Porphyrins, J. Porphyrins Phthalocyanines, 17(10), 2013, 1035-1045.

27.       Uglov A. N., Averin A. D., Buryak A. K., Bessmertnykh-Lemeune A. G., Guilard R., Beletskaya I. P., Palladium-Catalyzed Amination in the Synthesis of Macrocycles Comprising Two Naphthalene And Two Polyamine Moieties, Macroheterocycles, 6(1), 2013, 33-39.

28.       Ermakova E., Michalak J., Meyer M., Arslanov V., Tsivadze A., Guilard R., Bessmertnykh-Lemeune A., Colorimetric Hg2+ Sensing in Water: from Molecules Towards Low-cost Solid Devices, Org. Lett., 15(3), 2013, 662–665.

29.       Sinelshchikova A. A., Nefedov S. E., Enakieva Yu. Yu., Gorbunova Yu. G., Tsivadze A. Yu., Kadish K. M., Chen P., Bessmertnykh-Lemeune A., Stern C., Guilard R., Unusual Formation of a Stable 2D Copper Porphyrin Network, Inorg. Chem., 52(2), 2013, 999-1008.

30.        Mitrofanov A., Bessmertnykh-Lemeune A., Stern C., Guilard R., Gulyukina N., Beletskaya, I., Palladium-Catalyzed Synthesis of Mono- and Diphosphorylated 1,10-Phenanthrolines, Synthesis, 44(24), 2012, 3805-3810.

31.       Birin K. P., Gorbunova Yu. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A. G., Guilard, R., DFT/B3LYP Insight into Nucleophilic meso-Amination of 5,15-Diarylporphyrins, Macroheterocycles 5(4-5), 2012, 338-342.

32. Vinogradova E. V., Enakieva Yu. Yu., Nefedov S. E., Birin K. P., Tsivadze A. Yu., Gorbunova Yu. G., Bessmertnykh-Lemeune A., Stern C., and Guilard R., Synthesis and Self-organization of Zinc (Dialkoxyphosphoryl)porphyrins in the Solid State and in Solution, Chem.–Eur. J., 18(47), 2012, 15092-15104.

33.     Kadish K. M., Chen P., Enakieva Yu. Yu., Nefedov S. E., Gorbunova Yu. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A., Stern C., Guilard R., Electrochemical and Spectroscopic Studies of Poly(diethoxyphosphoryl)-porphyrins, J. Electroanal. Chem., 656(1-2), 2011, 61-71.

34.       Ranyuk E., Morkos Douaihy C., Bessmertnykh A., Guilard R., Preparation, Characterization and Photophysical Properties of Hybrid Materials fromRrareEearth Complexes of Phosphonato-substituted DOTAM Derivatives, New J. Chem., 35(6), 2011, 1189-1193.

35.        Averin A. D., Kobelev S. M., Anokhin M. V., Bessmertnykh-Lemeune A. G., Guilard R., Beletskaya I. P., Palladium-catalyzed Amination Reaction in the Synthesis of Nitrogen- and Oxygen-containing Macrocycles and Macropolycycles, Targets in Heterocyclic Systems, (15),  2011, 193-225.

36.        Ranyuk E., Uglov A., Meyer M., Bessmertnykh-Lemeune A., Denat F., Averin A., Beletskaya I., Guilard R., Rational Design of Aminoanthraquinones for Colorimetric Detection of Heavy Metal Ions in Aqueous Solution,Dalton Trans., 40(40), 2011, 10491-10502.

37.       Averin A. D., Uglov A. N., Beletskaya I. P., Bessmertnykh A. G., Guilard R., Palladium-catalyzed
Amination of Dihaloarenes: A Simple and Efficient Approach to Polyazamacrocycles.
In: Heterocyclic Compounds. Synthesis, Properties, Application. Chapter 4. Nova Science Publishers,Inc., 2010, pp. 119-146.

38.       Beletskaya I. P., Averin A. D., Bessmertnykh A. G., Denat F., Guilard R., Palladium-catalyzed Amination in the Synthesis of Polyazamacrocycles, Russ. J. Org. Chem., 46(7), 2010, 947-967.

39.       Averin A. D., Uglov A. N., Beletskaya I. P., Bessmertnykh A. G., Guilard R., Palladium-catalyzed Arylation of Polyamines. In: Advances in Chemistry Research. Nova Science Publishers, Inc., 4, 2010, 269-296.

 

1.         Abel A. S., Averin A. D., Lemeune A., Beletskaya I. P., Pd-catalyzed amination of 1,10-phenanthrolines and its application for detection of heavy metal ions. 21st International symposium on homogeneous catalysis (ISHC 2018), Amsterdam, Netherlands, 2018, (P. 242).

2.         Abel A. S., Averin A. D., Lemeune A., Beletskaya I. P., Pd-catalyzed amination of halogeteroarenes in the synthesis of luminescent macrocyclic compounds. International conference "1st Russian-Chinese Workshop on Organic and Supramolecular Chemistry" (RCWOSC-1), Kazan, Russia, 2018 (P. 51).

3.        Brandès S., Feuchter H., Michalak J., Lemeune A.,> Porous Metal–Organic Frameworks Based on N–Ligands for Selective Gas Adsorption and Catalysis>, Congrès SCF Grand-Est; Mulhouse, France, 2017. (P. >65).

4.       Lemeune A., Brandès S., Michalak J., Mitrofanov A. Yu., Zr-based MOFs with 1,10-Phenanthroline Linker for Copper-catalyzed Reactions, 5th International Conference on Multifunctional, Hybrid and Nanomaterials, Lisbon, Portugal, 2017 (Abstr. P3.114).

5.       Mitrofanov A. Yu., Lemeune A., Brandès S., Guilard R., Beletskaya I. P., Development of Porous Heterogeneous Metallocomplex Catalysts Based on Titania. 5th International Conference on Multifunctional, Hybrid and Nanomaterials, Lisbon, Portugal, 2017 (Abstr. P1.112).

6.         Feuchter H., Brandès S., Lemeune A., Rousselin Y., Triazamacrocycle-functionalized Metal-Organic Frameworksfor selective CO2 adsorption. 5th International Conference on Multifunctional, Hybrid and Nanomaterials, Lisbon, Portugal, 2017 (Abstr. P1.118).

7.       Abdulaeva I. A.,Lemeune A., Birin K. P., Gorbunova Yu. G.,Imidazole-fused meso-Tetraarylporphyrins with Phosphonate Anchoring Group for Catalytic Oxidation Reactions,3rd International Green Catalysis Symposium, Rennes, France,2017, (P 47).

8.         Lemeune A., Brandès S., Mitrofanov A., Fleuchter H., Michalak J., Beletskaya I., Heterogenized Copper Complexes with 1,10-Phenanthroline Ligands for Sustainable Catalysis,3rd International Green Catalysis Symposium, Rennes, France, 2017 (P 49).

9.        Ermakova E., Meyer M., Bessmertnykh-Lemeune A., Guilard R., Raitman O., Kalinina M., Arslanov V. Optical Sensors for Monitoring of Mercury and Copper Cations in Aqueous Solutions, International Symposia on Metal Complexes (ISMEC 2017), Dijon, France, 2017 (P. 185).

10.       Lemeune A., Brandès S., Mitrofanov A., Michalak J., Beletskaya I., Porous Nanomaterials Based on Copper Complexes with 1,10-Phenanthrolines for Sustainable Catalysis, EuropaCat 2017, Florence, Italy, 2017 (Abstr. P3.68).

11.       Abel A. S., Averin A. D., Lemeune A., Denat F., Beletskaya I. P., Palladium-catalyzed arylation of polyamines with 6-bromoquinoline in the synthesis fluorescent chemosensors for metal cations. National Russian scientific conference “Modern problems of organic chemistry”, Novosibirsk, Russia, 2017 (P. 141).

12.       Abel A. S., Kharlamova A. D., Averin A. D., Lemeune A. G., Beletskaya . I. P., Novel fluorescent amino derivatives of 2,3-diphenylquinoxaline. The International Jubilee Congress dedicated A.E. Favorsky. Irkutsk, Russia, 2017 (P. 180).

13.       Volostnykh M .V., Enakieva Yu. Yu., Gorbunova Yu. G., Lemeune A., Nefedov S. E., Tsivadze A. Yu., Guilard, R., Supramolecular assembly and hybrid organo-inorganic materials based on meso-phosphonate-substituted porphyrins. XI International Conference on the chemistry of porphyrins and their analogues, Ivanovo, Russia, 2017 (P. 36).

14.       Abel A. S., Averin A. D., Bessmertnykh-Lemeune A. G., Beletskaya I. P., Ruthenium(II)–phenanthrolines Bearing Polyamine Receptors: Synthesis and Metal Ion Recognition, International Conference "Dombay Organic Conference Cluster" (DOCC-2016), Dombay, Russia, 2016 (P. 117).

15.       Lemeune A., Brandès S., Mitrofanov A., Michalak J., Guilard, R., Beletskaya I.,Rational Design and Elaboration of Molecular Materials Based on Metal Complexes with 1,10-Phenanthrolines for Catalysis,11th International Congress on Catalysis and Fine Chemicals (CAFC11), Lyon, France, 2016 (Abstr.O29).

16.       Lemeune A., Meyer, M., Ermakova E., Arslanov V., Tsivadze A., Averin A., Beletskaya I., Polyamino-9,10-anthraquinones for Sensing Toxic Metal Ions in Aqueous Media, XX Mendeleev Congress on General and Applied Chemistry, Ekaterinbourg, Russia, 2016(Abstr. Vol. 5, (English) P. 229).

17.       Brandès S., Feuchter H.,Lemeune A., Guilard, R. Mitrofanov A., Beletskaya I.,Porous Organic-inorganic Materials Based on N-ligands for Selective Gas Adsorption and Catalysis, XX Mendeleev Congress on General and Applied Chemistry, Ekaterinbourg, Russia, 2016(Abstr. Vol. 5, (English) P. 225).

18.       Gorbunova Yu. G., Lemeune A., Guilard R., Tsivadze A. Yu., Survey in porphyrin chemistry in the framework of CNRS - RAS joint laboratory “LAMREM”,XX Mendeleev Congress on General and Applied Chemistry, Ekaterinbourg, Russia, 2016(Abstr. Vol. 5, (English) P. 227).

19.       Volostnykh M. V.,Enakieva Yu. Yu.,Gorbunova Yu. G., Bessmertnykh-Lemeune A., Nefedov S. E., Gorbunova Yu. G., Tsivadze A. Yu., Guilard, R, Porphiryn phosphonates: synthesis and applications,XII International Conference "Synthesis and Application of Porphyrins and their analogues" (ICPC-12), Kostroma, Russia, 2016 (P. 53).

20.       Enakieva Yu. Yu., Gorbunova Yu. G., Bessmertnykh-Lemeune A., Tsivadze A. Yu., Guilard R, Synthesis of meso–meso Direct Linked Porphyrin Dimers Bearing Phosphonate Substituents for Supramolecular Assembly.XII International Conference "Synthesis and Application of Porphyrins and their analogues" (ICPC-12), Kostroma, Russia, 2016 (P. 106).

 

Organic chemistry, detection and molecular materials: chemistry of small ring compounds, synthesis of macrocyclic ligands, transition metal-catalyzed reactions, chemosensors and molecular materials for detection, molecular recognition, self-assembly, sol-gel processes, functionalization of surfaces, hybrid materials based on metal-phosphonates, porous molecular materials, heterogenized catalysts. 

2011/2019 Director of International Associated Laboratory «LAboratory of Macrocyclic systems and RElated Materials» (LAMREM) created by CNRS, Burgundy University, Russian Academy of Sciences and Russian Foundation for Basic Researches.